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ChemInform Abstract: Active Site Models for Galactose Oxidase and Related Enzymes

โœ Scribed by Shinobu Itoh; Masayasu Taki; Shunichi Fukuzumi

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
31
Category
Article
ISSN
0931-7597

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Galactose oxidase (GO) contains one copper ion at its active site and performs a two-electron oxidation of primary alcohols to aldehydes, coupled with a reduction of O 2 to eomer in 68 % yield. The entire sequence was performed in 24 linear steps from (S)-malic acid. The material thus obtained was s