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ChemInform Abstract: “Absolute” Asymmetric Synthesis Using the Chiral Crystal Environment: Photochemical Hydrogen Abstraction from Achiral Acyclic Monothioimides in the Solid State.
✍ Scribed by M. SAKAMOTO; M. TAKAHASHI; M. SHIMIZU; T. FUJITA; T. NISHIO; I. IIDA; K. YAMAGUCHI; S. WATANABE
- Book ID
- 112029197
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
Due to the matrix effect of the crystal lattice, irradiation of alcohol 2 could be produced, depending on which enantiomorphic form of the chiral crystal was irradiated. As ketone 1 yields 2 diastereoselectively as the main product (97% de). Furthermore, the chiral crystal environment in the ketone
Solid State Photochemical Reaction of Achiral N-(β,γ-Unsaturated Carbonyl)thiocarbamate to Optically Active Thiolactone in the Chiral Crystalline Environment. -The solid-state photoreaction, leading to optically active γ-thiolactone (II), proceeds via intramolecular [2 + 2] thietane formation and s