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ChemInform Abstract: A Total Synthesis of (-)-Hemiasterlin Using N-Bts Methodology.

✍ Scribed by Edwin Vedejs; Chutima Kongkittingam


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
33
Category
Article
ISSN
0931-7597

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Total Synthesis of Clerocidin via a Novel, Enantioselective Homoallenylboration Methodology. -The key steps in the synthesis of the title compound (VI) are stereoselective homoallenylboration of the aldehyde (II) and regio-and stereoselective epoxidation of the resulting diene (IV). -(XIANG, A. X.;