Methyl ~-C-lactoside ([3-D-Galp-C-(l-->4)-~-Glcp-OMe) is stereoselectively synthesized by radical coupling of phenyl Se-[~ -D-galactopyranoside 5 onto exo-methylene-sugar 4, which are temporarily connected through a silaketal tether.
ChemInform Abstract: A Stereoselective Synthesis of Methyl β-C-Lactoside Through the Tether Approach.
✍ Scribed by G. RUBINSTENN; J.-M. MALLET; P. SINAY
- Book ID
- 101869769
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Stereoselective Synthesis of β-Hydroxycyclohexanones. -A stereoselective route to β-hydroxycyclohexanones is reported. Thus Takai alkylidenation of the aldol (I) followed by desilylation and a novel anionic oxy-Cope rearrangement provides an enolate which undergoes 6-(enolendo)-exo-trig cyclization
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v