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ChemInform Abstract: A Short Synthesis of the Antileukemic Sesquiterpene (+)-Caparratriene Employing Aqueous Wittig Chemistry.

✍ Scribed by Priyabrata Das; James McNulty


Book ID
102060310
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
41
Category
Article
ISSN
0931-7597

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An efficient, stereoselective method for the synthesis of (+)-caparratriene based on an aqueous Wittig reaction has been developed. A functionalized triethylallyl ylide reacted under various conditions with (+)-citronellal to deliver (+)-caparratriene in only three steps with excellent overall yield

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