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A convergent synthesis of the immunosuppressant FTY720 employing aqueous Wittig chemistry

✍ Scribed by Janice Calzavara; James McNulty

Book ID
113929911
Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
256 KB
Volume
52
Category
Article
ISSN
0040-4039

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A short synthesis of the anti-leukemic sesquiterpene (+)-caparratriene employing aqueous Wittig chemistry
✍ Priyabrata Das; James McNulty πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 237 KB

An efficient, stereoselective method for the synthesis of (+)-caparratriene based on an aqueous Wittig reaction has been developed. A functionalized triethylallyl ylide reacted under various conditions with (+)-citronellal to deliver (+)-caparratriene in only three steps with excellent overall yield