ChemInform Abstract: A Selective Procedure for α-Alkenylation of Enones Involving Pd- Catalyzed Alkenyl-Alkenyl Coupling and Its Application to a Convergent and Efficient Synthesis of Nakienone B.
✍ Scribed by M. POUR; E. NEGISHI
- Book ID
- 112038549
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
Nakienone A was synthesized for the first time from 3-methoxy-2-cyclopentenone, dienyl iodide 7, and LiCI-I2OMOM in 8 steps in 26% overall yield with full control of the alkene geometry using the Pal-catalyzed cross coupling reaction of a cyclopentenylzinc derivative 6a with 7 as a key step.
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