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ChemInform Abstract: A Radical Cyclization Strategy for the Concise Total Synthesis of (.+-. )-Geissoschizine.

โœ Scribed by H. TAKAYAMA; F. WATANABE; M. KATAJIMA; N. AIMI

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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A Concise, Stereoselective Synthesis of (ยฑ)-Geissoschizine. -The stereoselective synthesis of (ยฑ)-geissoschizine (VIII) is based on the addition of the enolate derived from 1-acetylindole (I) to the pyridinium salt (II) and cyclization of the resultant 1,4-dihydropyridine. -(BENNASAR, M.-L.;