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ChemInform Abstract: A Protected Form of (1S,2R,3S,4R)-4-Aminocyclopentane-1,2,3-triol, a Useful Precursor to 5′-Nor Carbocyclic Nucleosides.

✍ Scribed by Vasanthakumar P. Rajappan; Vishnumurthy R. Hegde; Stewart W. Schneller

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200201225

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A Convenient Stereoselective Synthesis of (1R,2S,3R,4S)-3-(Neopentyloxy)isoborneol. -The first regio-and stereoselective synthesis of the title compound (VI), a valuable chiral auxiliary, is developed starting from the camphorquinone (I) in six steps and 48% overall yield. -