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ChemInform Abstract: A Novel Transformation of 2-Acetylthiophene and Its Halogen Derivatives under Vilsmeier Reaction Conditions.

โœ Scribed by Valerii Z. Shirinian; Leonid I. Belen'kii; Mikhail M. Krayushkin


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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A Novel One-Pot Synthesis of 2-Aminoquinolines from Arylazidoketones by Cyclization under Vilsmeier Conditions. -The reaction of Vilsmeier reagent with 2-azidophenyl ketones is investigated. 1-(2-Azidophenyl)ethanone (I) yields a mixture of the aminoquinolines (III) and (IV). Unexpectedly, the anal