ChemInform Abstract: A Novel Synthesis Route to Rare Earth Polyborates.
β Scribed by Peichao Lu; Yingxia Wang; Jianhua Lin; Liping You
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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A Novel Route to Monoanomeric Spiroketals. -The readily prepared spiroketal C2-acetal (XI) undergoes regioselective reaction with allylsilane. However, a monoanomeric spiroketal (XIII) is unexpectedly the major product. The sequence provides a model for the synthesis of the CD subunit of altohyrtin