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ChemInform Abstract: A Novel Synthesis of trans-Enynes from Substituted Tetrahydropyrans.

✍ Scribed by Burhan Karadogan; Neil Edwards; Philip J. Parsons

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

A Novel Synthesis of trans-Enynes from Substituted Tetrahydropyrans. -Cleavage of 3-bromo-2-ethynyltetrahydropyrans such as (I) and (V) with BuLi or in situ generated cobaloxime(I) results in a novel method for the synthesis of trans-enynes [cf. (III) and (VI)]. -(KARADOGAN, BURHAN;

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