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ChemInform Abstract: Synthesis of Tetrahydropyrans from Sugar Lactones.

✍ Scribed by J. C. ESTEVEZ; A. J. FAIRBANKS; G. W. J. FLEET

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Synthesis of Tetrahydropyrans from Sugar Lactones.

-A series of Ξ³-gluco, Ξ³-allo and Ξ΄-altro hexonolactones and their C-2 triflates are synthesized. The possible mode of cyclization of these materials, and in particular the propensity for tetrahydropyran formation, is investigated for each series under various sets of reaction conditions. -(ESTEVEZ,

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