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ChemInform Abstract: A Novel Synthesis of Allyl Selenides by Reaction of an Organosamarium Reagent with Alkyl Selenocyanates.

โœ Scribed by You Huang; Ruyu Chen

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
31
Category
Article
ISSN
0931-7597

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โœ B. H. LIPSHUTZ; K. WOO; T. GROSS; D. J. BUZARD; R. TIRADO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 31 KB

Alkylations of Functionalized Organozinc Reagents with Allylic Epoxides Catalyzed by a Cyanocuprate. -Transmetalation of the title reagents with either LiCuCN(Me) or Li2CuCN(Me)2 affords a cyanocuprate which selectively transfers the zinc substituents to allylic epoxides, thus establishing a novel