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ChemInform Abstract: A Novel Stereoselective Route to Trifluoromethylated Vinyl Sulfones.

✍ Scribed by Yanchang Shen; Guoping Wang; Jie Sun


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.


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A Novel Stereoselective Route to Some Uncommon Amino Acids. -An efficient synthesis of the D-erythro-Ξ²-methylaspartic acid analogue (VIII) is achieved in six steps. Evans' aldol reaction is utilized followed by Weinreb amide formation and Mitsunobu inversion to achieve the necessary stereochemistry