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ChemInform Abstract: A Novel Pentaannulation Reaction of Iminium Ions.

✍ Scribed by A. R. OFIAL; H. MAYR

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199728083

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A Novel Pentaannulation Reaction of Imin

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## Abstract The preformed iminium salts (1a–1d)‐SbCl react with (1,1‐dimethylallyl)trimethylsilane 2 in dichloromethane at ambient temperature to give the pyrrolidinium salts (3a–3d)‐SbCl in high yield. In addition, small amounts of the ene products 4c‐SbCl and 4d‐SbCl have also been detected.

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