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ChemInform Abstract: A Novel MCPBA Oxidation: p-Quinols and Epoxyquinols from Phenols.

✍ Scribed by B. A. SOLAJA; D. R. MILIC; M. J. GASIC

Book ID
112037913
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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A Novel Allylic Hydroxylation of Sterically Hindered Olefins by Fe-Porphyrin-Catalyzed mCPBA Oxidation. -Triterpenes such as (I) bearing a sterically hindered olefin readily undergo a novel allylic hydroxylation by MCPBA in the presence of iron(III) tetrakis(pentafluorophenyl)porphyrin chloride as