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ChemInform Abstract: A Novel C—C Bond Forming Reaction of Aryl- and Alkenylsilanols. A Halogen-Free Mizoroki—Heck Type Reaction.

✍ Scribed by K. HIRABAYASHI; Y. NISHIHARA; A. MORI; T. HIYAMA

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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Synthesis of Oxygen Heterocycles via a Palladium-Catalyzed C-O Bond-Forming Reaction. -The first synthesis of cyclic aryl ethers by an intramolecular Pd-catalyzed ipso substitution of an aryl halide with an alcohol is described. This process is functional group tolerant and produces five-, six-, an