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ChemInform Abstract: A Novel Approach to 1-Monosubstituted 1,2,3-Triazoles by a Click Cycloaddition/Decarboxylation Process.

✍ Scribed by Mei Xu; Chunxiang Kuang; Zhuo Wang; Qing Yang; Yubo Jiang

Publisher
John Wiley and Sons
Year
2011
Weight
43 KB
Volume
42
Category
Article
ISSN
0931-7597

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## Abstract Aryl azides **1** were treated with allenylmagnesium bromide (**2**) to generate 1,5‐disubstituted butynyl‐1__H__‐1,2,3‐triazoles **3** in a domino fashion, which upon Cu^I^‐catalyzed 1,3‐dipolar cycloaddition with aryl azides **4** afforded novel bis‐1__H__‐1,2,3‐triazoles **5** in qua