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ChemInform Abstract: A New Synthesis of (-)-Mesembrine Employing Sharpless AD Reaction and New Radical-Initiated Reaction.

✍ Scribed by T. YOSHIMITSU; K. OGASAWARA

Book ID
112031296
Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
27
Category
Article
ISSN
0931-7597

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A New Radical Vinylation Reaction of Iodides and Dithiocarbonates. -A novel method for the radical olefination of aliphatic iodides is presented based on sulfone chemistry. The introduction of phenylvinyl, mono-, or dichlorovinyl groups into the iodides is achieved by generation of the correspondin