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ChemInform Abstract: A New Synthesis of Bis-Enaminones via Acylation of Ketones.

✍ Scribed by Gunther Buehrdel; Rainer Beckert; Eva Petrlikova; Petra Herzigova; Vera Klimesova; Jan Fleischhauer; Helmar Goerls


Publisher
John Wiley and Sons
Year
2009
Weight
40 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: A Simple Synthesis
✍ C. BOGA; L. FORLANI; P. E. TODESCO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 2 views

A Simple Synthesis of New Carbinols from Bis(2-benzothiazolyl) Ketone. -The addition of Grignard reagents to the title compund (II) affords the corresponding carbinols (IV) under mild conditions in excellent yields without any side products. Even bulky nucleophiles give almost quantitative yields.