ChemInform Abstract: A New Synthesis of Bis-Enaminones via Acylation of Ketones.
β Scribed by Gunther Buehrdel; Rainer Beckert; Eva Petrlikova; Petra Herzigova; Vera Klimesova; Jan Fleischhauer; Helmar Goerls
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 40 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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A Simple Synthesis of New Carbinols from Bis(2-benzothiazolyl) Ketone. -The addition of Grignard reagents to the title compund (II) affords the corresponding carbinols (IV) under mild conditions in excellent yields without any side products. Even bulky nucleophiles give almost quantitative yields.