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ChemInform Abstract: A New Procedure for α-Hydroxylation of Ketones Using Thallium(III) p-Nitrobenzenesulfonate (TNS).

✍ Scribed by J. C. LEE; C. PARK; Y. CHOI


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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Tetrakis(dimethylamino)ethylene (TDAE) as a Useful Reductant of Some Chlorodifluoromethylated Ketones. A New Approach for the Synthesis of α,α-Difluoroketone Derivatives. -Reduction of chlorodifluoromethylated ketones with TDAE as an effective reductant generates α,α-difluoroacetyl anions, which ar