Paracyclophane-1,9-diene (1) is readily deprotonated at upon treatment with zinc(II) chloride in 1,2-dichloroethane to give the indene-annelated [2.2]paracyclophane 9 (72%) and its vinylic positions with BuLi to give the monolithium derivative 2 and -in the presence of TMEDA -even the 1,9-/ the bis(
ChemInform Abstract: A New Method for the Selective Bridge Functionalization of [2.2]Paracyclophanediene — Indenyl-Anellated [2.2]Paracyclophanedienes and Their Iron Complexes.
✍ Scribed by H. A. BUCHHOLZ; J. HOEFER; M. NOLTEMEYER; A. DE MEIJERE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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