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ChemInform Abstract: A New Method for the Synthesis of 2,3-Aziridino-2,3-dideoxyhexonamides and Their Conversion into 3-Amino-2,3-dideoxyhexenoic Acids.

✍ Scribed by C. JOERGENSEN; C. PEDERSEN; I. SOETOFTE

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

A

New Method for the Synthesis of 2,3-Aziridino-2,3dideoxyhexonamides and Their Conversion into 3-Amino-2,3dideoxyhexenoic Acids.

-New 2,3-aziridino-2,3-dideoxyhexonamides (VII) and (IX) can be prepared from the lactones (I) and (VIII) via treatment of the mesylates with aqueous ammonia. The diastereomerically pure carboxamides are precursors for 3-amino-2,3-dideoxyhexenoic acids. - (JOERGENSEN,

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