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ChemInform Abstract: A New Chelation-Assistance Mode for a Ruthenium-Catalyzed Silylation at the C—H Bond in Aromatic Ring with Hydrosilanes.

✍ Scribed by Fumitoshi Kakiuchi; Kimitaka Igi; Mitsutaka Matsumoto; Tomoo Hayamizu; Naoto Chatani; Shinji Murai


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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Rhodium-Catalyzed Reaction of N-(2-Pyridinyl)piperazines with CO and Ethylene. A Novel Carbonylation at a C-H Bond in the Piperazine Ring. -The electronic nature of substituents, both on the 4-nitrogen and in the pyridine ring, affects significantly the reactivity of the substrates in the novel tit