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ChemInform Abstract: A New C2-Symmetric Chiral Bisphosphine Ligand Containing a Bioxazole Backbone: Highly Enantioselective Hydrosilylation of Ketones.

โœ Scribed by S. LEE; C. W. LIM; C. E. SONG; I. O KIM

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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โœ P. J. PYE; K. ROSSEN; R. A. REAMER; N. N. TSOU; R. P. VOLANTE; P. J. REIDER ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB ๐Ÿ‘ 1 views

Mild Conditions. -A new chiral bis-phosphine ligand with a paracyclophane backbone is prepared and used as ligand in Rh-catalyzed hydrogenations of dehydroamino acid esters such as (I) with high enantioselectivity. -(PYE, P.