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ChemInform Abstract: A New and General One-Pot Synthesis of Propargyl Alcohols from Esters.

โœ Scribed by Min Jung Chae; Ah Ram Jeon; Tom Livinghouse; Duk Keun An

Publisher
John Wiley and Sons
Year
2011
Weight
26 KB
Volume
42
Category
Article
ISSN
0931-7597

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Efficient One-Pot Synthesis of Propargylstannanes from Propargylic Alcohol Derivatives via Allenyltitaniums. -The reaction of propargylic carbonates (I) with a Ti(OiPr) 4 /iPr-MgCl reagent combination followed by treatment with Bu 3 SnCl affords mixtures of propargylstannanes (III) and allenylstann