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ChemInform Abstract: A New and Efficient Conversion of Olefins into Thiiranes Using Diethoxyoxophosphoranesulfenyl Chloride.

โœ Scribed by J. KOWARA; A. SKOWRONSKA; J. MICHALSKI; G. CAPOZZI

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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A new and efficient conversion of olefin
A new and efficient conversion of olefins into thiiranes using diethoxyoxophosphoranesulfenyl chloride
โœ Jacek Kowara; Aleksandra Skowrรณnska; Jan Michalski; Giuseppe Capozzi ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 164 KB ๐Ÿ‘ 1 views

An expedient synthesis of thiiranes is described that involves electrophilic addition of diethoxyoxophosphoranesulfenyl chloride to alkenes followed by fluoride anion promoted conversion of the intermediate adducts into thiiranes.