A new and efficient conversion of olefins into thiiranes using diethoxyoxophosphoranesulfenyl chloride

✍ Scribed by Jacek Kowara; Aleksandra Skowrónska; Jan Michalski; Giuseppe Capozzi

• Publisher: John Wiley and Sons
• Year: 1997
• Tongue: English
• Weight: 164 KB
• Volume: 8
• Category: Article
• ISSN: 1042-7163
• DOI: 10.1002/(sici)1098-1071(1997)8:5<429::aid-hc7>3.0.co;2-3

✦ Synopsis

An expedient synthesis of thiiranes is described that involves electrophilic addition of diethoxyoxophosphoranesulfenyl chloride to alkenes followed by fluoride anion promoted conversion of the intermediate adducts into thiiranes.