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ChemInform Abstract: A Highly Stereoselective Construction of Glycosyl-β-(1→4)-galactoside Linkages by Reductive Cleavage of Cyclic Orthoesters.

✍ Scribed by Hiro Ohtake; Takamasa Iimori; Shiro Ikegami

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Highly Stereosele
ChemInform Abstract: A Highly Stereoselective Construction of β-Glycosyl Linkages by Reductive Cleavage of Cyclic Sugar Orthoesters.
✍ Hiro Ohtake; Naoto Ichiba; Shiro Ikegami 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 43 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: A Highly Stereosele
ChemInform Abstract: A Highly Stereoselective β-(1→4)-Glycosidic Bond Formation by Reductive Cleavage of Cyclic Orthoesters.
✍ T. IIMORI; H. OHTAKE; S. IKEGAMI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB

A Highly Stereoselective β-(1→4)-Glycosidic Bond Formation by Reductive Cleavage of Cyclic Orthoesters. -Reduction of the orthoester (I) under the conditions shown provides the desired glycoside (II) with high β-selectivity. Application of a LiAlH4/AlCl3 reagent to the glycosidic spiro-orthoesters