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ChemInform Abstract: A Highly Regioselective Approach to Multiple Adducts of C60 Governed by Strain Minimization of Macrocyclic Malonate Addends.

✍ Scribed by Uwe Reuther; Torsten Brandmueller; Wolfgang Donaubauer; Frank Hampel; Andreas Hirsch

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
33
Category
Article
ISSN
0931-7597

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A Highly Regioselective Approach to Mult
A Highly Regioselective Approach to Multiple Adducts of C60 Governed by Strain Minimization of Macrocyclic Malonate Addends
✍ Uwe Reuther; Torsten Brandmüller; Wolfgang Donaubauer; Frank Hampel; Andreas Hir 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 522 KB

New macrocyclic malonates 2-5 have been prepared by reaction of malonyl dichloride with alkanediols. Reactions of these cyclo-[n]-alkylmalonates with C60 are highly regioselective. The macrocycles containing identical alkyl spacers selectively form bis- and trisadducts of C60 with rotational symmetr