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A Highly Regioselective Approach to Multiple Adducts of C60 Governed by Strain Minimization of Macrocyclic Malonate Addends

✍ Scribed by Uwe Reuther; Torsten Brandmüller; Wolfgang Donaubauer; Frank Hampel; Andreas Hirsch


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
34 KB
Volume
8
Category
Article
ISSN
0947-6539

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A Highly Regioselective Approach to Mult
✍ Uwe Reuther; Torsten Brandmüller; Wolfgang Donaubauer; Frank Hampel; Andreas Hir 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 522 KB

New macrocyclic malonates 2-5 have been prepared by reaction of malonyl dichloride with alkanediols. Reactions of these cyclo-[n]-alkylmalonates with C60 are highly regioselective. The macrocycles containing identical alkyl spacers selectively form bis- and trisadducts of C60 with rotational symmetr