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ChemInform Abstract: A Highly Diastereoselective Cyclocarbonylation of Allene-Aldehyde Mediated by Mo(CO)6: Synthesis of Bicyclic Lactones.

✍ Scribed by Kyoung-Jun Ko; Sang-Hoon Kim; Yurim Kim; Dongwon Min; Chan-Mo Yu


Publisher
John Wiley and Sons
Year
2008
Weight
33 KB
Volume
39
Category
Article
ISSN
0931-7597

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## Abstract The bromination of aldehydes (I) in the presence of a chiral binaphthyl catalyst (BNS) followed by reduction of the intermediate α‐bromoaldehyde gives rise to bromohydrins (II) with high enantioselectivity.