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ChemInform Abstract: A General Solution to the Modular Synthesis of Polyketide Building Blocks by Kanemasa Hydroxy-Directed Nitrile Oxide Cycloadditions.

✍ Scribed by Jeffrey W. Bode; Nina Fraefel; Dieter Muri; Erick M. Carreira

Publisher: John Wiley and Sons
Year: 2010
Weight: 36 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200137134

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Abstract

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A General Solution to the Modular Synthesis of Polyketide Building Blocks by Kanemasa Hydroxy-Directed Nitrile Oxide Cycloadditions

✍ Jeffrey W. Bode; Nina Fraefel; Dieter Muri; Erick M. Carreira 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB 👁 2 views

A single, convenient reaction protocol and the same set of readily available starting materials suffice for the modular synthesis of all possible polypropionate diastereomers. This general method for the diastereoselective synthesis of syn, anti, and methyl ketone aldol adducts utilizes a powerful M