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ChemInform Abstract: A General and Diastereoselective Synthesis of 1,2-cis-Hexofuranosides from 1,2-trans-Thiofuranosyl Donors.

✍ Scribed by Muriel Gelin; Vincent Ferrieres; Daniel Plusquellec


Publisher
John Wiley and Sons
Year
2001
Weight
39 KB
Volume
32
Category
Article
ISSN
0931-7597

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The general formation of 1,2-trans-thioglycofuranosides derived from D-galactose, D-glucose and D-mannose was readily accomplished starting from the corresponding alkyl glycofuranosides via per-O-acetyl-hexofuranoses as key synthons. Glycosidation of ethyl or phenyl perbenzylated 1,2-transthiofurano

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