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ChemInform Abstract: A Facile Synthetic Method of Herbicidal 2,3-Dihydro-3-methylene-2- substituted-phenyl-1H-isoindol-1-one Derivatives.

โœ Scribed by J. N. KIM; E. K. RYU

Book ID
112032361
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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A new synthetic route to highly enantioe
A new synthetic route to highly enantioenriched 3-substituted-2,3-dihydro-1H-isoindol-1-ones
โœ Eric Deniau; Dieter Enders; Axel Couture; Pierre Grandclaudon ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 164 KB

A concise and efficient synthesis of highly enantioenriched 3-alkyl and 3-aryl-2,3-dihydro-1H-isoindolinones is reported. The key step relies on the diastereoselective reduction of the N-acylhydrazonium salts generated by acidic treatment of hemiaminal precursors bearing the (S)-2-methoxymethylpyrro