## Abstract Ethyl 5‐substituted 7‐(methylthio)‐5__H__‐1‐thia‐3,5,6,8‐ tetra‐azaacenaphthylene‐2‐carboxylates (5a‐f) representing a new heterocyclic system were prepared by acid‐catalyzed cyclocondensation of ethyl 5‐amino‐4‐(substituted amino)‐2‐(methylthio)thieno[2,3‐__d__]pyrimidine‐6‐carboxylate
✦ LIBER ✦
ChemInform Abstract: A Facile Synthesis of 5H-1-Thia-3,5,6,8-tetraazaacenaphthylenes.
✍ Scribed by S. TUMKEVICIUS
- Book ID
- 112023811
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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Ethyl 3-amino-4-chlorothieno[3,2-c]quinoline-2-carboxylate (4) is a versatile synthon, prepared by reacting an equimolar amount of 2,4-dichloroquinoline-3-carbonitrile (1) with ethyl mercaptoacetate (2). Ethyl 5-alkyl-5H-1-thia-3,5,6-triazaaceanthrylene-2-carboxylates 9a-c, novel perianellated tetra