ChemInform Abstract: A Facile Stereoselective Synthesis of (3aR*,4R*,6aS*)-4-(Hydroxymethyl) -3,3a,4,6a-tetrahydrocyclopenta(b)furan-2-one and Other Useful Cyclopentanoid Building Blocks.
β Scribed by G. ZANONI; G. VIDARI
- Book ID
- 112023771
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Asymmetric Pd-catalyzed allylic alkylations of 2-acetoxymalonates with 2-cyclopentenyl chloride are described. With the cymantrene based phosphinooxazoline 2 as chiral ligand enantiomeric excess of> 99 % and > 90 % yield were obtained. Alkylation products were transformed in three steps to ( + )- (3
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