A facile stereoselective synthesis of (3aR*,4R*,6aS*)-4-(hydroxymethyl)- 3,3a,4,6a-tetrahydrocyclopenta[b]furan- 2-one and other useful cyclopentanoid building blocks.
β Scribed by Zanoni, Giuseppe; Vidari, Giovanni
- Book ID
- 111653994
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 647 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Asymmetric Pd-catalyzed allylic alkylations of 2-acetoxymalonates with 2-cyclopentenyl chloride are described. With the cymantrene based phosphinooxazoline 2 as chiral ligand enantiomeric excess of> 99 % and > 90 % yield were obtained. Alkylation products were transformed in three steps to ( + )- (3
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