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ChemInform Abstract: A Facile Stereoselective Route to a C/D-Ring Synthon for 20-Epi-22- oxavitamin D3 Analogues.

✍ Scribed by S. HATAKEYAMA; T. IKEDA; H. IRIE; C. IZUMI; H. MORI; K. UENOYAMA; H. YAMADA; M. NISHIZAWA

Book ID: 112028059
Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199608265

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## Enzymatic Kinetic Resolution of 5-Hydroxy-4-oxa-endotricyclo(5.2.1.02, 6)dec-8-en-3-ones: A Useful Approach to D-Ring Synthons for Strigol Analogues with Remarkable Stereoselectivity. -Racemic tricyclic hydroxy lactones (I) and (V) are resolved employing a lipase-catalyzed acetylation reaction