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ChemInform Abstract: A Facile Method for the Transformation of Acetals and Ketals to Aldehydes and Ketones.

โœ Scribed by S.-H. WU; Z.-B. DING

Book ID
112020526
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
26
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Functional Transfor
ChemInform Abstract: Functional Transformation of Aldehydes and Ketones via Homolytic Induced Decomposition of Unsaturated Peroxy Acetals and Peroxy Ketals.
โœ L. Moutet; D. Bonafoux; M. Degueil-Castaing; B. Maillard ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 2 views

The induced decomposition of the unsaturated peroxy acetal (IV) in the presence of CCl 4 or ethyl iodoacetate leads to its chloro-or iododecarbonylation with good yields. This reaction is also applied to the monoperoxy ketal (VIII) and the diperoxy ketal (X) of cyclohexanone. The title decomposition