ChemInform Abstract: A Facile Entry to the Taxane AB Ring System by Cyclopropyl-Carbinyl- Rearrangement of Tricyclo(5.3.1.01,7)undecanols.
β Scribed by W. THIELEMANN; H. J. SCHAEFER; S. KOTILA
- Book ID
- 112028340
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The selective control cyclopropyl bond cleavage of tricyclo [5.3.1.01,7]undecan-2-one by photochemical electron transfer produces a new approach to the construction of the carbon skeleton of the [A,B] ring system of the carbocyclic frame of taxane.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The Cyclopropylalkylidenecyclopropane Thermal Double Ring Expansion. A Novel Route to the Bicyclo[5.3.1]undecane Skeleton of the AB Ring System of Taxanes. -The mechanism of the reaction is explained by the initial formation of a diradical followed by opening to a homoallylic biradical which closes