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ChemInform Abstract: A Dirhodium(II)—Carbenoid Route to (-)- and (+)-Geissman—Waiss Lactone: Synthesis of (1R,7R,8R)-(-)-Turneforcidine.

✍ Scribed by Andrew G. H. Wee


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of (R)- a
✍ S.-I. MURAHASHI; H. OHTAKE; Y. IMADA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB 👁 1 views

Synthesis of (R)-and (S)-3-(tert-Butyldimethylsilyloxy)-1-pyrroline N-Oxides -Chiral Nitrones for Synthesis of Biologically Active Pyrrolidine Derivative, Geissman-Waiss Lactone. -Tungstatemediated oxidation of the chiral Tbs-protected 3-hydroxypyrrolidines (II) provides the required nitrones (III)