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ChemInform Abstract: A Conjugate Addition-Elimination Route to Alkenoyltrimethylsilanes.

โœ Scribed by R. F. CUNICO; C. ZHANG


Book ID
112024625
Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
27
Category
Article
ISSN
0931-7597

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โœ Kevin Blades; Jonathan M. Percy ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 229 KB

Cerium-mediated conjugate additions of (diethoxyphosphinoyl) difluoromethyllithium to cyclic vinyl sulfoxides proceeded smoothly; thermal suifoxide elimination afforded the products of formal vinylation, attaching the difluoromethylenephosphonato group to an alkenyl carbon atom. With acyclic vinyl s