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ChemInform Abstract: A Chiral Bis-Sulfoxide Ligand in Late-Transition Metal Catalysis; Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Electron-Deficient Olefins.

✍ Scribed by Ronaldo Mariz; Xinjun Luan; Michele Gatti; Anthony Linden; Reto Dorta


Publisher
John Wiley and Sons
Year
2008
Weight
43 KB
Volume
39
Category
Article
ISSN
0931-7597

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## Abstract An efficient rhodium complex catalyst system was developed by using a class of simple __tert__‐butanesulfinylphosphines as bidentate ligands, which solely bear sulfur chirality and combine the advantages of both sulfoxide and phosphine ligands. Excellent activities (in 0.5 hour, up to 9