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ChemInform Abstract: A Catalytic and Enantioselective Synthesis of trans-2-Amino-1-aryltetralins.

✍ Scribed by Saumen Hajra; Biswajit Maji; Dipakranjan Mal


Publisher
John Wiley and Sons
Year
2009
Weight
30 KB
Volume
40
Category
Article
ISSN
0931-7597

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A Catalytic and Enantioselective Synthes
✍ Saumen Hajra; Biswajit Maji; Dipakranjan Mal πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 215 KB πŸ‘ 2 views

## Abstract magnified image The bis‐oxazoline‐copper complex‐catalyzed aziridination of alkenes followed by an intramolecular Friedel–Crafts alkylation of the tethered and __in situ__ generated aziridine provides a one‐pot, general and efficient method for the synthesis of __trans__‐2‐amino__‐__1‐

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the optical rotation ([a] D 25 ) of compound 6 should read +19.9 (c 1.0, CHCl 3 ) instead of Γ€ 19.9 (c 1.3, CHCl 3 ). Hence the absolute configurations of 2, 36, 6, 7 and 8 should correspond to those of the enantiomers. The authors apologize for this error. The corresponding corrections have been ma