ChemInform Abstract: 3-Chloropropyl and 4-Chlorobutyl Phenyl Ethers as Sources of 1,3-Dilithiopropane and 1,4-Dilithiobutane: Sequential Reaction with Carbonyl Compounds.
β Scribed by Francisco Foubelo; Sadiq A. Saleh; Miguel Yus
- Book ID
- 101904402
- Publisher
- John Wiley and Sons
- Year
- 2000
- Weight
- 30 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The reaction of 3-chloropropyl phenyl ether (1) with lithium powder and a catalytic amount of DTBB (2.5% molar) in THF at -78Β°C followed by successive treatment with a carbonyl compound [El = ButCHO, Me2CO, (CH2)5CO] at -78 to 20Β°C and, after 1 h at this temperature, a second one [F~ = ButCHO, PhCHO
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