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ChemInform Abstract: 2,4,6-Trichloropyrimidine. Reaction with Ethanolamine and Diethanolamine.

✍ Scribed by T. J. DELIA; D. STARK; S. K. GLENN

Book ID
112024056
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
26
Category
Article
ISSN
0931-7597

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## Abstract The reaction of 2,4,6‐trichloropyrimidine 1 with a variety of 4‐substituted anilines 2 has been investigated. Monosubstitution occurs readily for all anilines except those containing strongly electron‐withdrawing groups. The yields of the isomeric products 3 and 4 parallel the Hammet co

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## Abstract The first reaction between 2,4,6‐trichloropyrimidine 1 and anionic nitrogen nucleophiles is described. Treatment of 1 with one equivalent of sodium amide gave mixtures of 4‐amino‐2,6‐dichloropyrimidine 2 and 2‐amino‐4,6‐dichloropyrimidine 3. Additional quantities of sodium amide failed