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ChemInform Abstract: 2,3-Epoxyperfluoro-2-methylpentane in Reactions with Urea and Thiourea.

✍ Scribed by T. I. Filyakova; L. V. Saloutina; A. Ya. Zapevalov; P. A. Slepukhin; M. I. Kodess; V. I. Saloutin


Publisher
John Wiley and Sons
Year
2011
Weight
30 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

Title epoxide (I) reacts with thiourea both in protic and aprotic solvents to furnish predominantly the unexpected product (III) generated by an intramolecular β€œhaloform” decomposition.


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ChemInform Abstract: Condensation of Tri
✍ V. YA. SOSNOVSKIKH πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 31 KB

Condensation of Trichloro-and Trifluoroacetonitriles with 4-Acylamino-4-methylpentan-2-ones. -Condensation of the title pentanones (I) with trihalogenoacetonitriles (II) proceeds in the presence of (N-ethylanilino)magnesium bromide to afford the (Ξ²-aminovinyl)-Ξ²'acylaminoketones (III) in low yields