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ChemInform Abstract: 2-(Phosphinoaryl)pyridine Ligands. Part 2. Asymmetric Allylic Alkylation of 2-Cycloalkenyl Carboxylate.

✍ Scribed by Katsuji Ito; Risa Kashiwagi; Sakiko Hayashi; Tatsuya Uchida; Tsutomu Katsuki

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 32
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200122028

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## Abstract __C__~2~‐Symmetrical, enantiopure 2,6‐di[1‐(1‐aziridinyl)alkyl]pyridines (DIAZAPs) were prepared by a high‐yielding, three‐step sequence starting from 2,6‐pyridinedicarbaldehyde and (__S__)‐valinol or (__S__)‐phenylglycinol. The new compounds were tested as ligands in palladium‐catalyze